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18729276. HYDROSILYLATION PROCESS PHOTOCATALYSED BY A MANGANESE COMPLEX (CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE)

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HYDROSILYLATION PROCESS PHOTOCATALYSED BY A MANGANESE COMPLEX

Organization Name

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

Inventor(s)

Raphaël Mirgalet of Lyon FR

Anthony Vivien of Villeurbanne FR

Clément Camp of Lyon FR

Laurent Veyre of JARDIN FR

Chloé Thieuleux of Villeurbanne FR

HYDROSILYLATION PROCESS PHOTOCATALYSED BY A MANGANESE COMPLEX

This abstract first appeared for US patent application 18729276 titled 'HYDROSILYLATION PROCESS PHOTOCATALYSED BY A MANGANESE COMPLEX

Original Abstract Submitted

The present invention relates to hydrosilylation reactions between a monosubstituted alkene compound and a compound comprising at least one hydrogen atom bonded to a silicon atom. More specifically, the invention relates to a process for the hydrosilylation of an unsaturated compound (A) that comprises at least one monosubstituted alkene function with a compound (B) that comprises at least one hydrosilane function, said process comprising the step of exposing said unsaturated compound (A) and said compound (B) to irradiation in the presence of a photocatalyst (C) consisting of a manganese carbonyl. This hydrosilylation reaction between an alkene compound and a compound comprising at least one hydrogen atom bonded to a silicon atom makes it possible, in particular, to cure silicone compositions by crosslinking.

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